(enH2)(4.5)[In(As(V)S4)3][As2(III)(μ-S2)S3]Cl and (enH2)MnAs(III)As(V)S6: two thioarsenates(III, V) with mixed-valent optical properties.
نویسندگان
چکیده
Two mixed-valent thioarsenates, namely (enH2)(4.5)[In(As(V)S4)3][As2(III)(μ-S2)S3]Cl (1) and (enH2)MnAs(III)As(V)S6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.
منابع مشابه
Simultaneous Spectrophotometric Determination of Vanadium(V) and Iron(III) in Micellar Medium by H-Point Standard Addition Method
H-Point Standard Addition Method (HPSAM) was applied for the simultaneous determination of V(V) and Fe(III). The method is based on the complex formation of V(V) and Fe(III) with chromazurol S (CAS) in acidic media and in the presence of cetyltrimethylammonium bromide (CTAB) as a micellizing agent. Acidic media and the presence of a micellar system improve selectivity and sensitivity. Fe (I...
متن کاملStudy of elastic and piezoelectric properties of two-dimensional hexagonal III-V binary compounds: First-principles calculations
In this work, using plane wave method in the framework of density-functional theory, we calculated clamped-ion and relaxed-ion elasticity, stress and strain piezoelectric independent coefficients for seven stable combinations of honeycomb monolayers XY (X:B,Al,Ga,In ; Y:N,P,As,Sb). The coefficients calculations by two methods of density functional perturbation theory (DFPT) and finite differenc...
متن کاملElectronic supporting information for Experimental and first-principles NMR analysis of Pt(II) complexes with O,O′-dialkyl dithiophosphate ligands
S1 Compound I X-ray XYZ coordinates . . . . . . . . . . . . . . . . 4 S2 Compound II X-ray XYZ coordinates . . . . . . . . . . . . . . . 4 S3 Compound III (molecule A) X-ray XYZ coordinates . . . . . . . 4 S4 Compound III (molecule B) X-ray XYZ coordinates . . . . . . . 5 S5 Compound IV (molecule A) X-ray XYZ coordinates . . . . . . . 5 S6 Compound IV (molecule B) X-ray XYZ coordinates . . . . ...
متن کاملAUDITORY BRAINSTEM RESPONSES (ABR) IN HYPERBILIRUBINEMIC NEWBORNS
To evaluate the changes of ABR values in hyperbilirubinemic newborns, 85 cases with severe jaundice (total bilirubin levels over 16 mg/dL and direct bilirubin less than 2 mg/dL) were selected from those admitted to Children's Medical Center by simple sampling method. These infants had no other problem except jaundice. ABR was taken before treatment in all cases and in some (10 cases) after...
متن کاملEvaluation of Compressive Mechanical Properties of the Radial Bone Defect Treated with Selected Bone Graft Substitute Materials in Rabbit
Objective- To determine the effect of selected bone graft on the compression properties of radialbone in rabbit.Design- Experimental in vivo study.Animals- A total of 45 adult male New Zealand white rabbits.Procedures- The rabbits were anesthetized and a one-cm-full thickness piece of radial bone wasremoved using oscillating saw in the all rabbit. The rabbits were divided into 5 groups on theba...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 43 7 شماره
صفحات -
تاریخ انتشار 2014